{"created":"2023-06-20T13:43:15.934439+00:00","id":973,"links":{},"metadata":{"_buckets":{"deposit":"71691754-086a-4857-86d0-2667fb9b1945"},"_deposit":{"created_by":2,"id":"973","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"973"},"status":"published"},"_oai":{"id":"oai:fut.repo.nii.ac.jp:00000973","sets":["1"]},"author_link":["11858","11857","11860","11852","11855","11859","11851","11856","11854","11853"],"item_10002_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2009-08-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"39","bibliographicPageEnd":"286","bibliographicPageStart":"279","bibliographic_titles":[{}]}]},"item_10002_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The crystal structure of a model complex for the active center in nitrite reductase、[Cu(II)(bis(2-pyridylmethyl)benzylamine)NO2.ClO4]2 has been determined by X-ray diffraction method at -170 degrees centigrade. The molecule has dimeric structure related by the crystallographic center of symmetry. The copper atom has the square bipyramidal coordination geometry with three nitrogen atoms in approximately planar bpa ligand (bpa; bis(2-pyridylmethyl)amine), two oxygen atoms in nitrite ion (NO2-), and an oxygen atom in nitrite ion of another half of the molecule. The cation - II interaction was found between copper atom and benzyl substituent resulting the long interatomic distances of Cu1-O2 = 2.698(3) and Cu2-O8 = 2.861(3) Å. Based on these distances, the nitrite ion is concluded to take end on coordination mode.","subitem_description_type":"Abstract"}]},"item_10002_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.57375/00000967","subitem_identifier_reg_type":"JaLC"}]},"item_10002_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"福井工業大学"}]},"item_10002_relation_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"TF00009426","subitem_relation_type_select":"NCID"}}]},"item_10002_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"18844502 / 18844456","subitem_source_identifier_type":"ISSN"}]},"item_10002_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"甲斐, 泰"}],"nameIdentifiers":[{"nameIdentifier":"11851","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"有澤, 宏章"}],"nameIdentifiers":[{"nameIdentifier":"11852","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"山口, 和也"}],"nameIdentifiers":[{"nameIdentifier":"11853","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"野尻, 正樹"}],"nameIdentifiers":[{"nameIdentifier":"11854","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"鈴木, 晋一郎"}],"nameIdentifiers":[{"nameIdentifier":"11855","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kai, Yasushi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"11856","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Arisawa, Hiroaki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"11857","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yamaguchi, Kazuya","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"11858","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nojiri, Masaki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"11859","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Suzuki, Shinnichiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"11860","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-04-12"}],"displaytype":"detail","filename":"kiyou3938.pdf","filesize":[{"value":"5.5 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"kiyou3938.pdf","url":"https://fut.repo.nii.ac.jp/record/973/files/kiyou3938.pdf"},"version_id":"105b7b92-4663-4ead-a194-4d446bb97c74"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"構造解析","subitem_subject_scheme":"Other"},{"subitem_subject":"錯体","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"亜硝酸還元酵素活性中心モデル錯体の構造化学(2)-CubpaBzNO2 錯体のX線結晶構造解析","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"亜硝酸還元酵素活性中心モデル錯体の構造化学(2)-CubpaBzNO2 錯体のX線結晶構造解析"},{"subitem_title":"Structural Chemistry of the Model Complexes for the Active Center in Nitrite Reductase -X-ray Structural Studies on CubpaBzNO2 Complexes","subitem_title_language":"en"}]},"item_type_id":"10002","owner":"2","path":["1"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-11-30"},"publish_date":"2009-11-30","publish_status":"0","recid":"973","relation_version_is_last":true,"title":["亜硝酸還元酵素活性中心モデル錯体の構造化学(2)-CubpaBzNO2 錯体のX線結晶構造解析"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-06-20T14:21:45.618964+00:00"}