{"created":"2023-06-20T13:43:15.485470+00:00","id":963,"links":{},"metadata":{"_buckets":{"deposit":"593bda5f-4c27-4387-b1f5-0c2e3234c9e5"},"_deposit":{"created_by":2,"id":"963","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"963"},"status":"published"},"_oai":{"id":"oai:fut.repo.nii.ac.jp:00000963","sets":["1"]},"author_link":["11806","11803","11805","11807","11809","11801","11804","11808","11810","11802"],"item_10002_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2009-08-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"39","bibliographicPageEnd":"278","bibliographicPageStart":"271","bibliographic_titles":[{}]}]},"item_10002_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The crystal structure of a model complex for the active center in nitrite reductase, Cu(II)(bis(2-pyridylmethyl)amine)NO2.ClO4, has been determined by X-ray diffraction method at -145 degrees centigrade. The copper atom has the square bipyramidal coordination geometry with three nitrogen atoms in planar bpa ligand (bpa; bis(2-pyridylmethyl)amine), two oxygen atoms in nitrite ion (NO2-), and an oxygen atom in ClO4 ion. Even though both oxygen atoms in nitrite ion are bonding to copper atom, the bond distances are quite different, Cu-O1 = 1.9726(14) and Cu-O2 = 2.5381(16)Å. Based on these distances, the nitrite ion is resulted to take chelate mode coordination with distinct bond distances.","subitem_description_type":"Abstract"}]},"item_10002_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.57375/00000957","subitem_identifier_reg_type":"JaLC"}]},"item_10002_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"福井工業大学"}]},"item_10002_relation_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"TF00009416","subitem_relation_type_select":"NCID"}}]},"item_10002_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"18844502 / 18844456","subitem_source_identifier_type":"ISSN"}]},"item_10002_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"甲斐, 泰"}],"nameIdentifiers":[{"nameIdentifier":"11801","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"青木, 将和"}],"nameIdentifiers":[{"nameIdentifier":"11802","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"山口, 和也"}],"nameIdentifiers":[{"nameIdentifier":"11803","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"野尻, 正樹"}],"nameIdentifiers":[{"nameIdentifier":"11804","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"鈴木, 晋一郎"}],"nameIdentifiers":[{"nameIdentifier":"11805","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kai, Yasushi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"11806","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Aoki, Masakazu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"11807","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yamaguchi, Kazuya","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"11808","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nojiri, Masaki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"11809","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Suzuki, Shinnichiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"11810","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-04-12"}],"displaytype":"detail","filename":"kiyou3937.pdf","filesize":[{"value":"5.9 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"kiyou3937.pdf","url":"https://fut.repo.nii.ac.jp/record/963/files/kiyou3937.pdf"},"version_id":"63051abd-42b1-4d62-a57e-61e1424764ec"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"錯体","subitem_subject_scheme":"Other"},{"subitem_subject":"構造解析","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"亜硝酸還元酵素活性中心モデル錯体の構造化学(1)-CubpaNO2 錯体のX線結晶構造解析","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"亜硝酸還元酵素活性中心モデル錯体の構造化学(1)-CubpaNO2 錯体のX線結晶構造解析"},{"subitem_title":"Structural Chemistry of the Model Complexes for the Active Center in Nitrite Reductase -X-ray Structural Studies on CubpaNO2 Complexes","subitem_title_language":"en"}]},"item_type_id":"10002","owner":"2","path":["1"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-11-30"},"publish_date":"2009-11-30","publish_status":"0","recid":"963","relation_version_is_last":true,"title":["亜硝酸還元酵素活性中心モデル錯体の構造化学(1)-CubpaNO2 錯体のX線結晶構造解析"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-06-20T14:21:54.163096+00:00"}