{"created":"2023-06-20T13:44:18.681749+00:00","id":2276,"links":{},"metadata":{"_buckets":{"deposit":"23f1a067-3d3d-485e-be18-f7325d97d9a7"},"_deposit":{"created_by":2,"id":"2276","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"2276"},"status":"published"},"_oai":{"id":"oai:fut.repo.nii.ac.jp:00002276","sets":["1"]},"author_link":["16769","16767","16768","16771","16775","16770","16773","16772","16776","16774"],"item_10002_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-06-30","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"48","bibliographicPageEnd":"90","bibliographicPageStart":"83","bibliographic_titles":[{"bibliographic_title":"福井工業大学研究紀要"}]}]},"item_10002_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"In this paper, we report an investigation of the two-photon ionization (TPI) of diphenylacetylene (DPA) in the presence of cyclodextrin (CD) by using 266-nm laser pulse irradiation. TPI of DPA within the laser flash (5 ns) generated a radical cation of DPA and hydrated electrons. The ionization quantum yield (Φion) of DPA in the presence of α-CD, β-CD, and γ-CD (1.0 ×10-2 M) were calculated to be 1.8 ± 0.1%, 1.3 ± 0.1 0x0.00000f66282e9p-1022nd 1.0 ± 0.1%, respectively. We suggested that this result induced by the stabilization energy arising from solvation and excimer formation, is due to the CD cavity size. When the concentration of CD was lowered to 1.0 × 10-3 M, the Φion of DPA decreased with the fluorescence lifetime (τ). On the whole, we found that the TPI of DPA in the presence of CD was influenced by the τ, the stabilization energy arising from solvation, and the excimer formation.","subitem_description_type":"Abstract"}]},"item_10002_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.57375/00002266","subitem_identifier_reg_type":"JaLC"}]},"item_10002_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"福井工業大学"}]},"item_10002_relation_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"TF10103121","subitem_relation_type_select":"NCID"}}]},"item_10002_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"原, 道寛"}],"nameIdentifiers":[{"nameIdentifier":"16767","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"鳥取, 央"}],"nameIdentifiers":[{"nameIdentifier":"16768","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"箕﨑, 知香"}],"nameIdentifiers":[{"nameIdentifier":"16769","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"上松, 伯章"}],"nameIdentifiers":[{"nameIdentifier":"16770","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"竹下, 達哉"}],"nameIdentifiers":[{"nameIdentifier":"16771","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Michihiro, Hara","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"16772","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Akira, Tottori","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"16773","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Chika, Minosaki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"16774","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Takanori, Uematsu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"16775","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Tatsuya, Takeshita","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"16776","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-05-12"}],"displaytype":"detail","filename":"083-090.pdf","filesize":[{"value":"4.9 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"083-090.pdf","url":"https://fut.repo.nii.ac.jp/record/2276/files/083-090.pdf"},"version_id":"abeedb5f-ae73-4a9e-b7bd-e9c0b0ff45d1"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Diphenylacetylene","subitem_subject_scheme":"Other"},{"subitem_subject":"Cyclodextrin","subitem_subject_scheme":"Other"},{"subitem_subject":"Two-Photon Ionization","subitem_subject_scheme":"Other"},{"subitem_subject":"Laser Flash Photolysis","subitem_subject_scheme":"Other"},{"subitem_subject":"Inclusion Complex","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"シクロデキストリンを用いたジフェニルアセチレンの2光子イオン化","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"シクロデキストリンを用いたジフェニルアセチレンの2光子イオン化"},{"subitem_title":"Two-Photon Ionization of Diphenylacetylene in the Presence of Cyclodextrin","subitem_title_language":"en"}]},"item_type_id":"10002","owner":"2","path":["1"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-07-24"},"publish_date":"2018-07-24","publish_status":"0","recid":"2276","relation_version_is_last":true,"title":["シクロデキストリンを用いたジフェニルアセチレンの2光子イオン化"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-06-20T13:57:24.483375+00:00"}