{"created":"2023-06-20T13:43:48.449619+00:00","id":1628,"links":{},"metadata":{"_buckets":{"deposit":"d3ed4314-ce60-4958-9ff7-2f585b990796"},"_deposit":{"created_by":2,"id":"1628","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"1628"},"status":"published"},"_oai":{"id":"oai:fut.repo.nii.ac.jp:00001628","sets":["1"]},"author_link":["14863","14859","14857","14856","14862","14860","14861","14858"],"item_10002_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-08-06","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"45","bibliographicPageEnd":"292","bibliographicPageStart":"285","bibliographic_titles":[{"bibliographic_title":"福井工業大学研究紀要"}]}]},"item_10002_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Resonance two-photon ionization (TPI) of Propoxur (o-isopropoxyphenyl methylcarbamate : MC), a typical agricultural chemical was demonstrated using 266-nm laser flash photolysis (LFP) technique in the presence of cyclodextrins (CDs) in aqueous solution. The formation of the MC/CDs inclusion complex was studied by MM2 calculations. Ionization of MC within the laser flash (5 ns) produced a water solvated electron. The electron was generated by two-photon excitation by means of simultaneous irradiation from a266-nm laser. The ionization quantum yield (Φion) obtained by LFP in the presence ofα-, β-and γ-CD were 0.35±0.02%, 0.15±0.01%and 0.61±0.01%, respectively, and it depended on the properties of the complexes with CDs. These behaviors suggest that the useful resonance two-photon ionization results from the complexes of MC and α-CD, β-CD and γ-CD, respectively. The Φion of MC in the presence of CDs (1.0×10-2M) is dependent on the stabilization energy of solvation. In addition, Φion of MC in the presence of CDs (1.0×10-3M) was dependent on the τ. This study suggests photolysis of agricultural chemicals in the presence of CDs in aqueous solvent using two-photon ionization of UV light irradiation.","subitem_description_type":"Abstract"}]},"item_10002_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.57375/00001622","subitem_identifier_reg_type":"JaLC"}]},"item_10002_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"福井工業大学"}]},"item_10002_relation_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"TF00010503","subitem_relation_type_select":"NCID"}}]},"item_10002_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"竹下, 達哉"}],"nameIdentifiers":[{"nameIdentifier":"14856","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"北畑, 香純"}],"nameIdentifiers":[{"nameIdentifier":"14857","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"笠羽, 祐太"}],"nameIdentifiers":[{"nameIdentifier":"14858","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"原, 道寛"}],"nameIdentifiers":[{"nameIdentifier":"14859","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Takeshita, Tatsuya","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"14860","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kitabata, Kasumi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"14861","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kasaba, Yuuta","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"14862","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hara, Michihiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"14863","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-04-12"}],"displaytype":"detail","filename":"285-292.pdf","filesize":[{"value":"6.6 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"285-292.pdf","url":"https://fut.repo.nii.ac.jp/record/1628/files/285-292.pdf"},"version_id":"eb98817d-9131-4bba-89c0-b4c88950bde6"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Resonance Two-Photon Ionization","subitem_subject_scheme":"Other"},{"subitem_subject":"Laser Flash Photolysis","subitem_subject_scheme":"Other"},{"subitem_subject":"Cyclodextrin","subitem_subject_scheme":"Other"},{"subitem_subject":"Propoxur","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"シクロデキストリン水溶液中におけるプロポクサーの2 光子イオン化","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"シクロデキストリン水溶液中におけるプロポクサーの2 光子イオン化"},{"subitem_title":"Resonance Two-Photon Ionization of Propoxur in Cyclodextrin Aqueous Solution","subitem_title_language":"en"}]},"item_type_id":"10002","owner":"2","path":["1"],"pubdate":{"attribute_name":"公開日","attribute_value":"2015-08-06"},"publish_date":"2015-08-06","publish_status":"0","recid":"1628","relation_version_is_last":true,"title":["シクロデキストリン水溶液中におけるプロポクサーの2 光子イオン化"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-06-20T14:10:49.211855+00:00"}