{"created":"2023-06-20T13:43:47.259561+00:00","id":1602,"links":{},"metadata":{"_buckets":{"deposit":"29e67277-ac1b-4dc7-b3a1-400d7c302494"},"_deposit":{"created_by":2,"id":"1602","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"1602"},"status":"published"},"_oai":{"id":"oai:fut.repo.nii.ac.jp:00001602","sets":["1"]},"author_link":["14753","14754","14755","14752","14758","14757","14756","14759"],"item_10002_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-07-21","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"46","bibliographicPageEnd":"187","bibliographicPageStart":"180","bibliographic_titles":[{"bibliographic_title":"福井工業大学研究紀要"}]}]},"item_10002_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Photoionization of benfluralin(N-butyl-N-ethyl-α, α, α-trifluoro-2, 6-dinitro-p-toluidine: Benf.) of typical agricultural chemical was achieved with two-photon two-step excitation by using 266-nm laser pulse irradiation in the presence of cyclodextrins (CDs). The formation of the Benf./CDs inclusion complex was studied by minimize energy of Molecular Mechanics program 2. Ionization of Benf. within the laser flash (5 ns)produced a radical cation of Benf. and hydrated electrons. The ionization quantum yield (Φion) of Benf. in the presence ofα-, β-and γ-CD calculated to be 6.2±0.1%, 16.0±1.0%and 3.3±0.1%, respectively, and it is due to the property of the Benf./CDs inclusion complex. The Φion of Benf. in the presence of CDs(1.0×10-2M)was dependent on the stabilization energy of solvation. In the case of CD concentration (1.0×10-3M),Φion of Benf. was also dependent on the stabilization energy of solvation. Additionally, we found that bulky substituted amino groups is important for the two-photon ionization (TPI)of agricultural chemical when compared with TPI of carbamate based agricultural chemicals. These results suggest the possibility of the photolysis of agricultural chemicals in aqueous solution by using TPI of UV light irradiation.","subitem_description_type":"Abstract"}]},"item_10002_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.57375/00001596","subitem_identifier_reg_type":"JaLC"}]},"item_10002_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"福井工業大学"}]},"item_10002_relation_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"TF00010477","subitem_relation_type_select":"NCID"}}]},"item_10002_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"竹下, 達哉"}],"nameIdentifiers":[{"nameIdentifier":"14752","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"佐々木, 美緒"}],"nameIdentifiers":[{"nameIdentifier":"14753","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"矢野, 篤"}],"nameIdentifiers":[{"nameIdentifier":"14754","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"原, 道寛"}],"nameIdentifiers":[{"nameIdentifier":"14755","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Takeshita, Tatsuya","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"14756","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sasaki, Mio","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"14757","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yano, Atsushi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"14758","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hara, Michihiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"14759","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-04-12"}],"displaytype":"detail","filename":"180-187.pdf","filesize":[{"value":"5.8 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"180-187.pdf","url":"https://fut.repo.nii.ac.jp/record/1602/files/180-187.pdf"},"version_id":"64232d73-f95e-4c9e-9264-d89b6dda7440"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Two-Photo Ionization","subitem_subject_scheme":"Other"},{"subitem_subject":"Laser Flash Photolysis","subitem_subject_scheme":"Other"},{"subitem_subject":"Cyclodextrin","subitem_subject_scheme":"Other"},{"subitem_subject":"Benfluralin","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"シクロデキストリン共存下におけるベンフルラリンの2光子イオン化","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"シクロデキストリン共存下におけるベンフルラリンの2光子イオン化"},{"subitem_title":"Two-Photon Ionization of Benfluralin in the Presence of Cyclodextrin","subitem_title_language":"en"}]},"item_type_id":"10002","owner":"2","path":["1"],"pubdate":{"attribute_name":"公開日","attribute_value":"2016-07-21"},"publish_date":"2016-07-21","publish_status":"0","recid":"1602","relation_version_is_last":true,"title":["シクロデキストリン共存下におけるベンフルラリンの2光子イオン化"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-06-20T14:11:09.874635+00:00"}