{"created":"2023-06-20T13:43:43.442200+00:00","id":1523,"links":{},"metadata":{"_buckets":{"deposit":"1baa9ab7-1328-403b-8213-4eddea7669d3"},"_deposit":{"created_by":2,"id":"1523","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"1523"},"status":"published"},"_oai":{"id":"oai:fut.repo.nii.ac.jp:00001523","sets":["1"]},"author_link":["14395","14396"],"item_10002_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-07-10","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"47","bibliographicPageEnd":"136","bibliographicPageStart":"129","bibliographic_titles":[{"bibliographic_title":"福井工業大学研究紀要"}]}]},"item_10002_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Flow microreactors can provide a revolutionary change on organic synthesis, because of the following characteristic features derived from their small size and flow nature: 1) fast mixing, 2) temperature control, 3) highly strict control of reaction condition. By taking advantage of these feature, chemical reactions which are very difficult or impossible in flasks can be achieved in flow microreactors. We have applied this protocol to selective monobromination of 2,2'-bithiophene with N-bromosuccinimide. After various trials of controlling reaction conditions, the yield of the undesired di-brominated product (5,5'-dibromo-2,2'-bithiophene) could be reduced to 1-2%. The most important factor in the microflow system was the combination of the flow rate and the equivalent of N-bromosuccinimide. This article is described the details of the progress to achieve good selectivity.","subitem_description_type":"Abstract"}]},"item_10002_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.57375/00001517","subitem_identifier_reg_type":"JaLC"}]},"item_10002_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"福井工業大学"}]},"item_10002_relation_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"TF00010398","subitem_relation_type_select":"NCID"}}]},"item_10002_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kurata, Hiroyuki"}],"nameIdentifiers":[{"nameIdentifier":"14395","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kurata, Hiroyuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"14396","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-04-12"}],"displaytype":"detail","filename":"129-136.pdf","filesize":[{"value":"6.9 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"129-136.pdf","url":"https://fut.repo.nii.ac.jp/record/1523/files/129-136.pdf"},"version_id":"bf8712fb-311e-4696-95d3-d576bee2a39a"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Flow Microreactor","subitem_subject_scheme":"Other"},{"subitem_subject":"Bromination","subitem_subject_scheme":"Other"},{"subitem_subject":"Thiophene","subitem_subject_scheme":"Other"},{"subitem_subject":"Organic Synthesis","subitem_subject_scheme":"Other"},{"subitem_subject":"Selective Functionalization","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"フローマイクロリアクターを用いた2/2'-ビチオフェンの選択的モノブロモ化反応","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"フローマイクロリアクターを用いた2/2'-ビチオフェンの選択的モノブロモ化反応"},{"subitem_title":"Selective Mono-Bromination of 2,2'-Bithiophene Using a Flow Microreactor","subitem_title_language":"en"}]},"item_type_id":"10002","owner":"2","path":["1"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-07-10"},"publish_date":"2017-07-10","publish_status":"0","recid":"1523","relation_version_is_last":true,"title":["フローマイクロリアクターを用いた2/2'-ビチオフェンの選択的モノブロモ化反応"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-06-20T14:12:15.142920+00:00"}