{"created":"2023-06-20T13:42:35.638585+00:00","id":124,"links":{},"metadata":{"_buckets":{"deposit":"23381bec-3d4e-4a3f-bcf7-ec670efa09df"},"_deposit":{"created_by":2,"id":"124","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"124"},"status":"published"},"_oai":{"id":"oai:fut.repo.nii.ac.jp:00000124","sets":["1"]},"author_link":["8870","8871","8868","8873","8877","8876","8875","8874","8872","8869"],"item_10002_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010-06-30","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"40","bibliographicPageEnd":"292","bibliographicPageStart":"286","bibliographic_titles":[{"bibliographic_title":"福井工業大学研究紀要"}]}]},"item_10002_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The crystal structure of the model complexes for the active center in nitrite reductase, Cu(II)(bis(2-pyridylmethyl)amine)PhEtR (complex 1; R=H2O, complex 2; R=NO2), have been determined by X-ray diffraction method at -160 degrees centigrade. The complex 1 has an H2O and two ClO4-ions in the crystal structure. The molecular structure of the complex 1 gives the original structure of this series of complexes before NO2 coordination to the copper atom. The Cu-O1(H2O) bond distance is 1.970(6)Å, which is the normal coordination bond distance of Cu-O. The complex 2 gives the 6-coordination copper atom with three sites occupied by bpa ligand, two by NO2- ion, and one by ClO4- ion. Even though both oxygen atoms in nitrite ion are bonding to copper atom, the bond distances are quite different, Cu-O1 = 1.962(2) and Cu-O2 = 2.544(3)Å. Based on these distances, the nitrite ion is resulted to take an asymmetrical chelate coordination with distinct bond distances.","subitem_description_type":"Abstract"}]},"item_10002_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.57375/00000118","subitem_identifier_reg_type":"JaLC"}]},"item_10002_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"福井工業大学"}]},"item_10002_relation_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"TF00008577","subitem_relation_type_select":"NCID"}}]},"item_10002_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"甲斐, 泰"}],"nameIdentifiers":[{"nameIdentifier":"8868","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"近江, 一恵"}],"nameIdentifiers":[{"nameIdentifier":"8869","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"山口, 和也"}],"nameIdentifiers":[{"nameIdentifier":"8870","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"野尻, 正樹"}],"nameIdentifiers":[{"nameIdentifier":"8871","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"鈴木, 晋一郎"}],"nameIdentifiers":[{"nameIdentifier":"8872","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kai, Yasushi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"8873","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ohmi, Kazue","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"8874","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yamaguch, Kazuya","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"8875","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nojiri, Masaki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"8876","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Suzuki, Shinnichiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"8877","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-04-12"}],"displaytype":"detail","filename":"kiyou4036.pdf","filesize":[{"value":"3.9 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"kiyou4036.pdf","url":"https://fut.repo.nii.ac.jp/record/124/files/kiyou4036.pdf"},"version_id":"e5a1250b-b31d-4463-9bbb-4fcb35877c00"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"亜硝酸還元酵素活性中心モデル錯体の構造化学(3) -CubpaPheEtR(R=H2O, NO2)錯体のX線結晶構造解析","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"亜硝酸還元酵素活性中心モデル錯体の構造化学(3) -CubpaPheEtR(R=H2O, NO2)錯体のX線結晶構造解析"},{"subitem_title":"Structural Chemistry of the Model Complexes for the Active Center in Nitrite Reductase –X-ray Structural Studies on CubpaPheEtR(R=H2O, NO2) Complexes","subitem_title_language":"en"}]},"item_type_id":"10002","owner":"2","path":["1"],"pubdate":{"attribute_name":"公開日","attribute_value":"2010-07-28"},"publish_date":"2010-07-28","publish_status":"0","recid":"124","relation_version_is_last":true,"title":["亜硝酸還元酵素活性中心モデル錯体の構造化学(3) -CubpaPheEtR(R=H2O, NO2)錯体のX線結晶構造解析"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-06-20T14:39:26.333312+00:00"}